Formation and Compaction of Sub-10 nm Transfer Films in Metal–Ceramic Fretting

Submitting author affiliation:
Advanced Research Center for Nanotechnology (ARCNL), Amsterdam, Netherlands

Beilstein Arch. 2026, 202617. https://doi.org/10.3762/bxiv.2026.17.v1

Published 15 May 2026

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Abstract

Nanoscale transfer in metal--ceramic fretting originates at microcontacts but has remained experimentally unresolved. Here, we use an atomic force microscopy (AFM)-based topographical difference method to visualize the formation of sub-10 nm transfer films at a sapphire--chromium interface subjected to fretting. Transfer proceeds via adhesive wear of chromium at micrometer-scale contacts, followed by plastic compaction of the chromium debris into a conformal ∼5 nm transfer film. Excess debris is expelled from the circular contact and accumulates in a curvature-defined peripheral ring around the contact. These results connect microcontact fracture, debris evolution, and nanoscale transfer-film formation in fretting contacts.

Keywords: adhesive wear; atomic force microscopy; fretting; metal--ceramic interface; transfer film

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When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Çiftçi, H. T.; Şahin, O.; Roch, T.; Weber, B. Beilstein Arch. 2026, 202617. doi:10.3762/bxiv.2026.17.v1

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