Synthesis of C70-fragment Buckybowls Having Alkoxy Substituents

  1. Yumi YakiyamaORCID Logo,
  2. Shota Hishikawa and
  3. Hidehiro SakuraiORCID Logo

Submitting author affiliation: Osaka University, Suita, Japan

Beilstein Arch. 2020, 202018. doi:10.3762/bxiv.2020.18.v1

Published 13 Feb 2020

  • Preprint

Abstract

Buckybowls of C70 fragment having two alkoxy groups were synthesized and their structural and optical properties were investigated by single crystal X-ray analysis and UV-vis spectroscopy. In the synthesis of dioxole derivative 5b, the regio isomer 5c was also produced. The yield of 5c was increased by increasing the reaction temperature, indicating that the rearrangement might involve the equilibrium between the Pd(IV) intermediates through the C-H bond activation.

Keywords: buckybowl; C70; rearrangement through C-H bond activation

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When a peer-reviewed version of this preprint is available in the Beilstein Journals, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Yakiyama, Y.; Hishikawa, S.; Sakurai, H. Beilstein Arch. 2020, 202018. doi:10.3762/bxiv.2020.18.v1

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