Beilstein Arch. 2020, 2020110. https://doi.org/10.3762/bxiv.2020.110.v1
Published 28 Sep 2020
A metal-free route for the synthesis of biarenes has been developed. This approach is based on the photoextrusion of a phosphate moiety occurring upon irradiation of biaryl- and triarylphosphates. The reaction involved an exciplex as the intermediate and it is especially suitable for the preparation of electron-rich biarenes.
Keywords: aryl phosphates; biarenes; metal-free synthesis; photochemistry; photoextrusion
|Format: PDF||Size: 3.6 MB||Download|
When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:
Qrareya, H.; Meazza, L.; Protti, S.; Fagnoni, M. Beilstein Arch. 2020, 2020110. doi:10.3762/bxiv.2020.110.v1
|Download RIS (Reference Manager)||Download BIB (BIBTEX)|
© 2020 Qrareya et al.; licensee Beilstein-Institut.
This is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited.
The license is subject to the Beilstein Archives terms and conditions: (https://www.beilstein-archives.org/xiv/terms)