Preparation of anthracene-based tetra-perimidine hexafluorophosphate and selective recognition for chromium(III) ion

Submitting author affiliation:
Tianjin Normal University, Tianjin, China

Beilstein Arch. 2019, 201981.

Published 02 Aug 2019

cc-by Logo


A novel anthracene-based tetra-perimidine hexafluorophosphate, 9,10-di{bi[2’-(N-ethylperimidinyl)ethyl]aminomethyl}anthracene PF6- (3) was prepared, and its structure was determined through X-ray analysis, 1H and 13C NMR. There are two soft (N-ethylperimidinylCH2CH2)2NCH2- moities on 9,10-locations of anthracene in the cationic part of 3. Compound 3 was used as a chemosensor to research the recognition ability for Cr3+ by fluorescence and UV titrations, IR, 1H NMR and HRMS. The results indicate that 3 is an effective chemosensor for Cr3+.

Keywords: Tetra-perimidine; Chemosensor; Chromium(III) ion.

Supporting Information

Format: DOCX Size: 1.8 MB   Download
Format: CIF Size: 353.4 KB   Download

How to Cite

When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Liu, Q.-X.; Yu, S.-C.; Zhao, Z.-X.; Yang, F.; Ding, Y. Beilstein Arch. 2019, 201981. doi:10.3762/bxiv.2019.81.v1

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.