Synthesis of Cyclic β-1,6-Oligosaccharides by Electrochemical Polyglycosylation of glucosamine monomers

Submitting author affiliation:
Tottori University, Tottori city, Japan

Beilstein Arch. 2024, 202423.

Published 16 Apr 2024

cc-by Logo
This preprint has not been peer-reviewed. When a peer-reviewed version is available, this information will be updated.


Synthesis of protected precursors of cyclic β-1,6-oligoglucosamines by electrochemical polyglycosylation of thioglycosides as a monomer is performed. The monomer with 2,3-oxazolidinone protecting group afforded the cyclic disaccharide exclusively. Cyclic oligosaccharides up to trisaccharide were obtained using the monomer with 2-deoxy-2-azido group.

Keywords: cyclic oligosaccharide; electrochemical glycosylation; glucosamine; polyglycosylation

Supporting Information

Format: PDF Size: 9.2 MB   Download

How to Cite

When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Rahman, M. A.; Endo, H.; Yamamoto, T.; Okushiba, S.; Sasaki, N.; Nokami, T. Beilstein Arch. 2024, 202423. doi:10.3762/bxiv.2024.23.v1

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.