Beilstein Arch. 2023, 202328. https://doi.org/10.3762/bxiv.2023.28.v1
Published 10 Jul 2023
A donor-p-acceptor (D–p–A) type pull–push compound, DMB-TT-TPA, of triphenylamine as a donor and dimesitylboron as an acceptor, linked through a thieno[3,2-b]thiophene (TT) p-conjugated linker bearing 4-MeOPh group, was designed, synthesized and fabricated as an emitter via a solution process for an organic light-emitting diode (OLED) application. DMB-TT-TPA exhibited absorption and emission maximums of 411 and 520 nm, respectively, with a mega Stokes shift of 109 nm and fluorescence quantum yields both in solid-state (41%) and in solution (86%). The optical properties were supported by computational chemistry using density functional theory for optimized geometry and absorption. A solution-processed OLED was fabricated using low turn-on voltage, which had performances with maximum power, current and external quantum efficiencies of 6.70% lm.W-1, 10.6 cd.A-1 and 4.61%, respectively.
Keywords: thienothiophene; triphenylamine; organoboron; OLED; solution processes
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Isci, R.; Ozturk, T. Beilstein Arch. 2023, 202328. doi:10.3762/bxiv.2023.28.v1
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