Polycyclic High Density Cage Compounds via Cross Metathesis

Submitting author affiliation:
Indian Institute of Technology-Bombay, Powai, Mumbai, Mumbai, India

Beilstein Arch. 2022, 202282. https://doi.org/10.3762/bxiv.2022.82.v1

Published 07 Oct 2022

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This preprint has not been peer-reviewed. When a peer-reviewed version is available, this information will be updated.


Synthesis of various highly functionalized caged systems suitable for high energy density materials was accomplished by utilization olefin cross metathesis strategy. Here we observed 100% E selectivity during cross-metathesis by using Grubbs II and N-tolyl Grubbs catalyst. The stereochemistry of olefin formed by cross-metathesis has been determined unambiguously by single-crystal X-ray diffraction study.

Keywords: Cookson’s dione, Grignard addition, Cross-metathesis and Cycloaddition

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When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Kotha, S.; Chaurasia, U. N. Beilstein Arch. 2022, 202282. doi:10.3762/bxiv.2022.82.v1

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