Beilstein Arch. 2022, 202282. https://doi.org/10.3762/bxiv.2022.82.v1
Published 07 Oct 2022
Synthesis of various highly functionalized caged systems suitable for high energy density materials was accomplished by utilization olefin cross metathesis strategy. Here we observed 100% E selectivity during cross-metathesis by using Grubbs II and N-tolyl Grubbs catalyst. The stereochemistry of olefin formed by cross-metathesis has been determined unambiguously by single-crystal X-ray diffraction study.
Keywords: Cookson’s dione, Grignard addition, Cross-metathesis and Cycloaddition
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Kotha, S.; Chaurasia, U. N. Beilstein Arch. 2022, 202282. doi:10.3762/bxiv.2022.82.v1
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