Excited State Dynamics for Visible Light Sensitization of Fast Photochromic Phenoxyl-Imidazolyl Radical Complex with Aryl Ketone

  1. Yoichi KobayashiORCID Logo,
  2. Yukie Mamiya,
  3. Katsuya MutohORCID Logo,
  4. Hikaru SotomeORCID Logo,
  5. Masafumi KogaORCID Logo,
  6. Hiroshi Miyasaka and
  7. Jiro Abe ORCID Logo

Submitting author affiliation: Aoyama Gakuin University, Sagamihara, Japan

Beilstein Arch. 2019, 201946. doi:10.3762/bxiv.2019.46.v1

Published 24 Jun 2019

  • Preprint

Abstract

Visible light sensitized photoswitches have been paid particular attention in the fields of life science and materials science because long-wavelength light reduces photodegradation, transmits deep inside of matters, and achieves the selective excitation in condensed systems.Among various photoswitch molecules, phenoxyl-imidazolyl radical complex (PIC) is a recently developed thermally-reversible photochromic molecule whose thermal back reaction can be tuned from tens of nanoseconds to tens of seconds by rational designs of the molecular structure. While the wide range of tunability of the switching speed of PIC opened up various potential applications, no photosensitivity to visible light limits its applications. In this study, we synthesized a visible light sensitized PIC derivative conjugated with a benzil unit. Femtosecond transient absorption spectroscopy revealed that the benzil unit acts as a singlet photosensitizer for PIC by the Dexter-type energy transfer. Visible light sensitized photochromic reactions of PIC are important for expanding the versatility of potential applications to life science and material science.

Keywords: biradical; energy transfer; photochromism; sensitizer; transient absorption spectroscopy

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When a peer-reviewed version of this preprint is available in the Beilstein Journals, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Kobayashi, Y.; Mamiya, Y.; Mutoh, K.; Sotome, H.; Koga, M.; Miyasaka, H.; Abe, J. Beilstein Arch. 2019, 201946. doi:10.3762/bxiv.2019.46.v1

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