Facile synthesis and assessment of 2-alkoxy-4-(4-hydroxyphenyl)-6-arylnicotinonitrile derivatives as new inhibitors for C1018-steel corrosion in HCl: A combined theoretical and experiential investigations 

  1. Hany Abd El-LateefORCID Logo,
  2. Antar A. AbdelhamidORCID Logo,
  3. Mounir A.A. Mohamed and
  4. Amr H. MoustafaORCID Logo

Submitting author affiliation: king Faisal university, Al-Ahsa, Saudi Arabia

Beilstein Arch. 2019, 2019147. doi:10.3762/bxiv.2019.147.v1

Published 26 Nov 2019

  • Preprint

Abstract

An effective and accessible synthesis of alkoxy arylnicotinonitriles was achieved via a four-component reaction of 4-hydroxybenzaldehyde, acetophenones, malononitrile in the presence of RONa. The synthesized alkoxy arylnicotinonitrile derivatives containing pyridine moiety were predestined as inhibitors for C1018-steel (CS) corrosion in 1.0 M HCl using potentiodynamic-polarization (PDP) and electrochemical impedance spectroscopy (EIS) methods. PDP plots were demonstrated that the arylnicotinonitriles behave as typical inhibitors of the mixed-type. They have also suppressed the CS corrosion at lower [inhibitor] and accomplished an inhibition capacity ranged from 87.6 to 98.2% in 0.7 mM. Their adsorption on the CS interface follows the isotherm model of Langmuir and they include both chemisorption and physisorption mechanisms, with a preference of chemisorption. The morphology of the CS surface was examined utilizing Fourier Transform Infrared Spectroscopy (FTIR) and field-emission scanning electron microscopy (FE-SEM). Moreover, Density Functional Theory (DFT) calculations confirm the empirical findings and the adsorption of arylnicotinonitrile derivatives on the CS interface.

Keywords: Arylnicotinonitrile derivatives; One-pot syntheses; Corrosion inhibition; Surface morphology; DFT calculations; EIS

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When a peer-reviewed version of this preprint is available in the Beilstein Journals, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Abd El-Lateef, H.; Abdelhamid, A. A.; Mohamed, M. A.; Moustafa, A. H. Beilstein Arch. 2019, 2019147. doi:10.3762/bxiv.2019.147.v1

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