Practical method to obtain α-acetoxyketones promoted by (diacetoxyiodo)benzene and acetic acid

  1. Osvaldo J Quintana-Romero,
  2. Jorge Camacho-Ruiz and
  3. Armando Ariza-CastoloORCID Logo

Submitting author affiliation: Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Mexico, Mexico

Beilstein Arch. 2019, 2019144. doi:10.3762/bxiv.2019.144.v1

Published 13 Nov 2019

  • Preprint

Abstract

By means of a simple procedure, we prepared α-acetoxyketones from a variety of enolizable ketones with PhI(OAc)2 in the presence of acetic acid. The selectivity of the reactions depended on steric hindrance, and some other reactions were observed, such as the formation of N=N or C=C double bonds through an oxidation reaction.

Keywords: Functionalization α to a carbonyl group; α-acetoxyketones; (diacetoxyiodo)benzene; selectivity

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When a peer-reviewed version of this preprint is available in the Beilstein Journals, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Quintana-Romero, O. J.; Camacho-Ruiz, J.; Ariza-Castolo, A. Beilstein Arch. 2019, 2019144. doi:10.3762/bxiv.2019.144.v1

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© 2019 Quintana-Romero et al.; licensee Beilstein-Institut.
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