Practical method to obtain α-acetoxyketones promoted by (diacetoxyiodo)benzene and acetic acid

Osvaldo J Quintana-Romero; Jorge Camacho-Ruiz; Armando Ariza-Castolo

doi:10.3762/bxiv.2019.144.v1

Practical method to obtain α-acetoxyketones promoted by (diacetoxyiodo)benzene and acetic acid

Osvaldo J Quintana-Romero,
Jorge Camacho-Ruiz and
Armando Ariza-Castolo

Submitting author affiliation: Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Mexico, Mexico

Beilstein Arch. 2019, 2019144. https://doi.org/10.3762/bxiv.2019.144.v1

Published 13 Nov 2019

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This preprint has not been peer-reviewed. When a peer-reviewed version is available, this information will be updated.

Abstract

By means of a simple procedure, we prepared α-acetoxyketones from a variety of enolizable ketones with PhI(OAc)₂ in the presence of acetic acid. The selectivity of the reactions depended on steric hindrance, and some other reactions were observed, such as the formation of N=N or C=C double bonds through an oxidation reaction.

Keywords: Functionalization α to a carbonyl group; α-acetoxyketones; (diacetoxyiodo)benzene; selectivity

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When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information:

Quintana-Romero, O. J.; Camacho-Ruiz, J.; Ariza-Castolo, A. Beilstein Arch. 2019, 2019144. doi:10.3762/bxiv.2019.144.v1

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aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

Practical method to obtain α-acetoxyketones promoted by (diacetoxyiodo)benzene and acetic acid

This preprint has not been peer-reviewed. When a peer-reviewed version is available, this information will be updated.

Abstract

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How to Cite

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