Beilstein J. Org. Chem.2006,2, No. 14, doi:10.1186/1860-5397-2-14
) in THF, with KF in the presence of 18-crown-6 in benzene, with cericammoniumnitrate IV (CAN) in aqueous acetonitrile and with H2-Pd/C in THF. No attempts were made to examine standard protic acid-catalysed desilylations such as AcOH in H2O/THF[16] or TFA/H2O in DCM[17] since we observed rapid
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Graphical Abstract
Scheme 1:
Acetyl migration products upon TBAF/THF treatment